Ep. 34: The Shining Silver Crystal: The Moon Princess Appears

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The new guardian, Sailor Venus, is also schoolgirl Minako Aino, accompanied by Artemis, a male white cat who also has the ability to speak. Forbidden by Queen Beryl to kill Tuxedo Mask, Zoisite challenges him to duel for the Rainbow Crystals. Usagi follows him, and they are forced to reveal their identities to each other. (Source: Wikipedia)