Ep. 14: Pochitan's First Outing!

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On their way to school, Anna and Mikuru are reprimanded by student council president, Rei, for bringing Pochitan in as a pouch. The next day, Pochitan, who was left to mind the CUREtto Detective Agency, rushes out on her own to deliver a letter to Anna and Mikuru. (Source: Pretty Cure! Wiki)