Ep. 3: Ichigo menghadapi Acidwire, roh Hollow dari kakak laki-laki Orihime Inoue yang telah meninggal.
Tayang pada 19 Oktober 2004

Ichigo discovers that one of his schoolmates, Orihime Inoue, is being stalked by her older brother's spirit who turned into the hollow Acidwire due to Orihime stopping her prayers for him, which makes him hesitate to fulfill his duty. As Ichigo is forced to use his power again, his qualms of killing hollows are rested and he finally submits to his purpose as a substitute Soul Reaper, killing Acidwire. Before he does so however, Orihime's older brother was able to revert to his kind and gentle nature, expressing his love for her and thanking her before being sent to the Soul Society, the place where Soul Reapers and souls reside, via Ichigo's zanpakutou. Agent of the Shinigami arc: (3/20)
Episode
- Ep. 1 · Ichigo memperoleh kekuatan Shinigami untuk mengalahkan Fishbone D setelah Rukia terluka
- Ep. 2 · Ichigo menjadi pengganti Rukia setelah ia kehilangan kekuatannya di kelasnya
- Ep. 3 · Ichigo menghadapi Acidwire, roh Hollow dari kakak laki-laki Orihime Inoue yang telah meninggal.
- Ep. 4 · Chad Menempati Kokatili Terkutuk yang Dihuni Jiwa Anak Laki-laki dan Hollow
- Ep. 5 · Chad bertarung melawan Shrieker yang tak terlihat dengan bantuan Rukia, sementara Ichigo memberikan pukulan penutup.
- Ep. 6 · Ichigo bertarung melawan permen jiwa buatan yang merusak reputasinya saat Rukia pergi.
- Ep. 7 · Ichigo bertarung melawan hollow sambil merebut kembali modsoul dan menempatkannya di dalam boneka singa bernama Kon