第 9 集: Black Star和Kid尋找傲慢的聖劍Excalibur，同時Death Scythe向Maka解釋魔劍的危險。
2008年6月2日 播出
Black Star and Kid learn about Excalibur, the Holy Sword whose legendary powers are said to surpass those of any other weapon and promise to bestow eternal glory to anyone who wields him. The two decide to search for Excalibur, but when they find him, they cannot stand his unbearable personality and end up abandoning him. Meanwhile, Death Scythe tries to cheer up Maka, who is still worried about Soul, and explains to her the origin of the Demon Sword, describing it as a weapon that has been devouring human souls and threatens to transform into a kishin, which is the reason the DWMA was founded to prevent from happening. (Source: Wikipedia)
集數
- 第 5 集 · 靈魂形態： Meister Stein 是否以最終戰力登場？
- 第 6 集 · Death the Kid與Thompson姐妹抵達DWMA，首日即與Soul和Black Star展開混亂對決。
- 第 7 集 · Maka和Soul調查義大利的一座教堂，Crona將魔劍Ragnarok藏匿於此
- 第 8 集 · 女巫美杜莎攜帶著巨大而可怕的靈魂？
- 第 9 集 · Black Star和Kid尋找傲慢的聖劍Excalibur，同時Death Scythe向Maka解釋魔劍的危險。
- 第 10 集 · Black Star和Tsubaki在敵對村莊中對抗吞噬靈魂的魔劍Masamune。
- 第 11 集 · 椿在魔劍中與政宗交戰，並吸收了她的第一顆靈魂
- 第 12 集 · Maka Albarn 克服對 Soul 受傷的恐懼，Medusa 則處理叛變的女巫。
- 第 13 集 · 瑪嘉與靈魂在倫敦對抗不死狼人弗利時，因頻率分歧而陷入苦戰。