Ep. 112: Call for Restoration

Gohan is powerless against the infected Piccolo. As Piccolo closes in for the kill, despite his attempts to free Kami and Mr. Popo from Garlic Jr.'s glass bottles, Krillin jumps in front of him (pushing Gohan out of the way to save him), and gets bitten (into unconsciousness and later turning into a demon) by Piccolo. Now Gohan seems to be the only hero left against his now infected friends, and as he is beaten nearly to death, the battle is almost over for him... or is it? (Source: Wikipedia)

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