Ep. 110: Ash faces Luana on Kumquat Island and struggles with a Double Battle partnership.
Aired on August 12, 1999

110
While visiting Kumquat Island, Ash encounters Luana, the final Orange Island Gym Leader, who initially confuses him for her son. Following an incident where Ash and Luana defend the island from Team Rocket, they proceed to the Gym for a Double Battle. Ash commands Pikachu and Charizard against Luana’s Marowak and Alakazam. However, the lack of coordination between Pikachu and Charizard threatens to prevent Ash from qualifying for the Orange League.
Episodes
- Ep. 106 · Ash and friends face trouble after Pikachu is captured and chained to Meowth on an island.
- Ep. 107 · Ash and Charizard bond after a freezing battle against a powerful Poliwrath
- Ep. 108 · Squirtle and his crew meet firefighting Wartortles after failing to extinguish a fire.
- Ep. 109 · Ash breaks Snorlax's Pokéball during battle while Team Rocket demands Pikachu for food
- Ep. 110 · Ash faces Luana on Kumquat Island and struggles with a Double Battle partnership.
- Ep. 111 · Tracey encounters Dr. Quackenpoker studying Magikarp evolution on Rind Island while Team Rocket intervenes.
- Ep. 112 · Misty seeks an antidote for Ash and Tracey after they are stunned by Spore on a small island.
- Ep. 113 · Ash faces a challenging six-on-six battle against Champion Drake on Pummelo Island
- Ep. 114 · Ash battles Drake's formidable Dragonite while striving for Orange League Championship victory