Ep. 6: Ash and N Free Captive Braviary from Team Plasma Grunts Nero and Bianco
Aired on February 21, 2013

6
Ash and his companions encounter N, who has liberated a Braviary previously held captive by Team Plasma. The group assists in transporting the injured bird to a Pokémon Center for medical care. However, their progress is interrupted by two Team Plasma Grunts named Nero and Bianco, who pursue them using a Seviper and a Zangoose respectively. During the ensuing confrontation, N risks his own safety to ensure Braviary's escape. After successfully freeing the Pokémon from its pursuers, N decides to accompany Ash and his friends as they continue their travels toward the White Ruins.
Episodes
- Ep. 2 · Ash and friends meet N on a boat to Reshiram ruins after Team Rocket attacks.
- Ep. 3 · New Gym Leader Arrives in Aspertia City with Cheren
- Ep. 4 · Team Plasma scientist Colress uses a machine to control Pokémon, causing attacks in Floccesy Town.
- Ep. 5 · Dragonite Aids Elly's Ampharos at Floccesy Ranch
- Ep. 6 · Ash and N Free Captive Braviary from Team Plasma Grunts Nero and Bianco
- Ep. 7 · Ash and friends encounter Halsey and his rescue team amid ideological conflict with N.
- Ep. 8 · Ash recalls Charizard at Kanto Fair and arranges a reunion match
- Ep. 9 · Colress Tests Advanced Machine on Dragon-Type Pokémon
- Ep. 10 · Anthea and Concordia reveal N's past to Ash after his injury by Colress.